台灣大學92學年度第二學期
課程名稱：化學鍵(Structure and Chemical Bonding) (2學分)
課程編號：203 12910
授課對象：化學系大學部學生 (大一以上選修)
授課老師：王瑜、金必耀教授
上課時間：週三56節(pm1:20-3:10)
上課地點：化三教室
課程網頁：http://www.ch.ntu.edu.tw/~byjin/course/chembond/index.html

化學鍵
本課程為一學期之課程，將介紹化學鍵的基本觀念、原理、 方法與應用。我們會從最基本的分子軌域理論與價鍵理論談起，從而導引學生了解有機、無機分子的電子結構、幾何構造與反應性。本課程將強調定性非數學的方法，且將利用許多分子軌域圖形讓學生學習到重要的化學概念，並能使用分子軌域解決化學結構與反應等問題。
References:Y. Jean, F. Volatron, and J. Burdett, An Introduction to Molecular Orbitals , Oxford University Press, 1993.Chemical Structure and Bonding, by Roger L. DeKock and Harry B.Grayl

Atomic Structure
Historical discoveries for Atomic Structure
Bohr Theory of Hydrogen Atom
Dual Properties of Electromagnetic Radiation and Matter
The Wave Equations and Hydrogen Atom
Many-Electron Atoms and Atomic Energy States

Lewis Structures and Valence Bond Theory
Lewis Structures
Multiple Bonds
Concept of Resonance
Valence Bond Theory
Hybrid Orbitals

Molecular Orbital Theory
Molecular orbital Energy Levels
Hydogen Molecule Ion and Hydrogen Molecule
Homonuclear Diatomic Molecules
Heteronuclear Diatomic Molecules
Photoelectron Spectra of Molecules

Electronic Structures of Polyatomic Molecules
Molecular Orbitals for Triatomic Molecules
Walsh Correlation Diagram
Molecular Orbitals for BH3 and NH3
Molecular Orbitals for CH4, CO2, and XeF4
Huckel Molecular Orbital Theory of Conjugated Systems